Development and Re‐Evaluation of Tourmaline Reference Materials for In Situ Measurement of Boron δ Values by Secondary Ion Mass Spectrometry     

Katharina Marger  Matthieu Harlaux  Andrea Rielli  Lukas P. Baumgartner  Andrea Dini  Barbara L. Dutrow  Anne‐Sophie Bouvier 《Geostandards and Geoanalytical Research》2020,44(3):593-615

Six tourmaline samples were investigated as potential reference materials (RMs) for boron isotope measurement by secondary ion mass spectrometry (SIMS). The tourmaline samples are chemically homogeneous and cover a compositional range of tourmaline supergroup minerals (primarily Fe, Mg and Li end‐members). Additionally, they have homogeneous boron delta values with intermediate precision values during SIMS analyses of less than 0.6‰ (2s). These samples were compared with four established tourmaline RMs, that is, schorl IAEA‐B‐4 and three Harvard tourmalines (schorl HS#112566, dravite HS#108796 and elbaite HS#98144). They were re‐evaluated for their major element and boron delta values using the same measurement procedure as the new tourmaline samples investigated. A discrepancy of about 1.5‰ in δ¹¹B was found between the previously published reference values for established RMs and the values determined in this study. Significant instrumental mass fractionation (IMF) of up to 8‰ in δ¹¹B was observed for schorl–dravite–elbaite solid solutions during SIMS analysis. Using the new reference values determined in this study, the IMF of the ten tourmaline samples can be modelled by a linear combination of the chemical parameters FeO + MnO, SiO₂ and F. The new tourmaline RMs, together with the four established RMs, extend the boron isotope analysis of tourmaline towards the Mg‐ and Al‐rich compositional range. Consequently, the in situ boron isotope ratio of many natural tourmalines can now be determined with an uncertainty of less than 0.8‰ (2s).  相似文献   

Biogeographical drivers of ragweed pollen concentrations in Europe     

Matyasovszky  István  Makra  László  Tusnády  Gábor  Csépe  Zoltán  Nyúl  László G.  Chapman  Daniel S.  Sümeghy  Zoltán  Szűcs  Gábor  Páldy  Anna  Magyar  Donát  Mányoki  Gergely  Erostyák  János  Bodnár  Károly  Bergmann  Karl-Christian  Deák  Áron József  Thibaudon  Michel  Albertini  Roberto  Bonini  Maira  Šikoparija  Branko  Radišić  Predrag  Gehrig  Regula  Rybníček  Ondřej  Severova  Elena  Rodinkova  Victoria  Prikhodko  Alexander  Maleeva  Anna  Stjepanović  Barbara  Ianovici  Nicoleta  Berger  Uwe  Seliger  Andreja Kofol  Weryszko-Chmielewska  Elżbieta  Šaulienė  Ingrida  Shalaboda  Valentina  Yankova  Raina  Peternel  Renata  Ščevková  Jana  Bullock  James M. 《Theoretical and Applied Climatology》2018,133(1-2):277-295

Theoretical and Applied Climatology - The drivers of spatial variation in ragweed pollen concentrations, contributing to severe allergic rhinitis and asthma, are poorly quantified. We analysed the...  相似文献   

The ecological implications of a Yakutian mammoth's last meal   总被引：1，自引：0，他引：1  

Bas van Geel  Andr Aptroot  Claudia Baittinger  Hilary H. Birks  Ian D. Bull  Hugh B. Cross  Richard P. Evershed  Barbara Gravendeel  Erwin J.O. Kompanje  Peter Kuperus  Dick Mol  Klaas G.J. Nierop  Jan Peter Pals  Alexei N. Tikhonov  Guido van Reenen  Peter H. van Tienderen 《Quaternary Research》2008,69(3):361-376

Part of a large male woolly mammoth (Mammuthus primigenius) was preserved in permafrost in northern Yakutia. It was radiocarbon dated to ca. 18,500 ¹⁴C yr BP (ca. 22,500 cal yr BP). Dung from the lower intestine was subjected to a multiproxy array of microscopic, chemical, and molecular techniques to reconstruct the diet, the season of death, and the paleoenvironment. Pollen and plant macro-remains showed that grasses and sedges were the main food, with considerable amounts of dwarf willow twigs and a variety of herbs and mosses. Analyses of 110-bp fragments of the plastid rbcL gene amplified from DNA and of organic compounds supplemented the microscopic identifications. Fruit-bodies of dung-inhabiting Ascomycete fungi which develop after at least one week of exposure to air were found inside the intestine. Therefore the mammoth had eaten dung. It was probably mammoth dung as no bile acids were detected among the fecal biomarkers analysed. The plant assemblage and the presence of the first spring vessels of terminal tree-rings of dwarf willows indicated that the animal died in early spring. The mammoth lived in extensive cold treeless grassland vegetation interspersed with wetter, more productive meadows. The study demonstrated the paleoecological potential of several biochemical analytical techniques.  相似文献   

Characterization of carbon monoxide,methane and nonmethane hydrocarbons in emerging cities of Saudi Arabia and Pakistan and in Singapore     

Barbara?BarlettaEmail authorView author&#;s OrcID profile  Isobel?J.?Simpson  Nicola?J.?Blake  Simone?Meinardi  Louisa?K.?Emmons  Omar?S.?Aburizaiza  Azhar?Siddique  Jahan?Zeb  Liya?E.?Yu  Haider?A.?Khwaja  Muhammad?A.?Farrukh  Donald?R.?Blake 《Journal of Atmospheric Chemistry》2017,74(1):87-113

We investigate the composition of 63 C₂-C₁₀ nonmethane hydrocarbons (NMHCs), methane (CH₄) and carbon monoxide (CO), in Jeddah, Mecca, and Madina (Saudi Arabia), in Lahore, (Pakistan), and in Singapore. We established a database with which to compare and contrast NMHCs in regions where ambient levels and emissions are poorly characterized, but where conditions are favorable to the formation of tropospheric ozone, and where measurements are essential for improving emission inventories and modeling. This dataset will also serve as a base for further analysis of air pollution in Western Saudi Arabia including, but not limited to, the estimation of urban emissions and long range pollution transport from these regions. The measured species showed enhanced levels in all Saudi Arabian cities compared to the local background but were generally much lower than in Lahore. In Madina, vehicle exhaust was the dominant NMHC source, as indicated by enhanced levels of combustion products and by the good correlation between NMHCs and CO, while in Jeddah and Mecca a combination of sources needs to be considered. Very high NMHC levels were measured in Lahore, and elevated levels of CH₄ in Lahore were attributed to natural gas. When we compared our results with 2010 emissions from the MACCity global inventory, we found discrepancies in the relative contribution of NMHCs between the measurements and the inventory. In all cities, alkenes (especially ethene and propene) dominated the hydroxyl radical (OH) reactivity (k _OH) because of their great abundance and their relatively fast reaction rates with OH.  相似文献   

The Romanian earthquake of August 30, 1986: A study based on GEOSCOPE very long-period and broadband data     

Tony Monfret  Anne Deschamps  Barbara Romanowicz 《Pure and Applied Geophysics》1990,133(2):367-379

The Romanian earthquake of August 30, 1986 is the second largest intermediate depth event in this area since the worldwide deployment of digital instrumentation, and the first one since the installation of GEOSCOPE network. It offers the unique opportunity to document this well-known but poorly understood zone of deep continental seismicity using high quality teleseismic data in different frequency bands. The source is well constrained both from very-long period surface wave data observed on GEOSCOPE stations and, independently, from body wave modelling at various worldwide stations. The depth obtained is approximately 140 kilometers, the seismic moment, 0.8 10²⁷ dyne-cm and the mechanism from both data sets is very similar to that of the previous 1940 and 1977 Vancrea events, indicating that these events, although having occurred at noticeably different depths, are expressions of the same tectonic process. However, from the detailed study of the source using broadband data, it can be inferred that the source presents much less complexity than the 1977 event.  相似文献   

Variation in biological and physicochemical parameters of the soil affected by uncontrolled landfill sites     

Barbara Breza-Boruta  Joanna Lemanowicz  Agata Bartkowiak 《Environmental Earth Sciences》2016,75(3):201

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An evaluation of unsupervised and supervised learning algorithms for clustering landscape types in the United States     

Jochen Wendel  Barbara P. Buttenfield  Lawrence V. Stanislawski 《制图学和地理信息科学》2016,43(3):233-249

Knowledge of landscape type can inform cartographic generalization of hydrographic features, because landscape characteristics provide an important geographic context that affects variation in channel geometry, flow pattern, and network configuration. Landscape types are characterized by expansive spatial gradients, lacking abrupt changes between adjacent classes; and as having a limited number of outliers that might confound classification. The US Geological Survey (USGS) is exploring methods to automate generalization of features in the National Hydrography Data set (NHD), to associate specific sequences of processing operations and parameters with specific landscape characteristics, thus obviating manual selection of a unique processing strategy for every NHD watershed unit. A chronology of methods to delineate physiographic regions for the United States is described, including a recent maximum likelihood classification based on seven input variables. This research compares unsupervised and supervised algorithms applied to these seven input variables, to evaluate and possibly refine the recent classification. Evaluation metrics for unsupervised methods include the Davies–Bouldin index, the Silhouette index, and the Dunn index as well as quantization and topographic error metrics. Cross validation and misclassification rate analysis are used to evaluate supervised classification methods. The paper reports the comparative analysis and its impact on the selection of landscape regions. The compared solutions show problems in areas of high landscape diversity. There is some indication that additional input variables, additional classes, or more sophisticated methods can refine the existing classification.  相似文献   

Basin evolution of Upper Cretaceous–Lower Cenozoic strata in the Malargüe fold‐and‐thrust belt: northern Neuquén Basin,Argentina          下载免费PDF全文

Elizabeth A. Balgord  Barbara Carrapa 《Basin Research》2016,28(2):183-206

The Andean Orogen is the type‐example of an active Cordilleran style margin with a long‐lived retroarc fold‐and‐thrust belt and foreland basin. Timing of initial shortening and foreland basin development in Argentina is diachronous along‐strike, with ages varying by 20–30 Myr. The Neuquén Basin (32°S to 40°S) contains a thick sedimentary sequence ranging in age from late Triassic to Cenozoic, which preserves a record of rift, back arc and foreland basin environments. As much of the primary evidence for initial uplift has been overprinted or covered by younger shortening and volcanic activity, basin strata provide the most complete record of early mountain building. Detailed sedimentology and new maximum depositional ages obtained from detrital zircon U–Pb analyses from the Malargüe fold‐and‐thrust belt (35°S) record a facies change between the marine evaporites of the Huitrín Formation (ca. 122 Ma) and the fluvial sandstones and conglomerates of the Diamante Formation (ca. 95 Ma). A 25–30 Myr unconformity between the Huitrín and Diamante formations represents the transition from post‐rift thermal subsidence to forebulge erosion during initial flexural loading related to crustal shortening and uplift along the magmatic arc to the west by at least 97 ± 2 Ma. This change in basin style is not marked by any significant difference in provenance and detrital zircon signature. A distinct change in detrital zircons, sandstone composition and palaeocurrent direction from west‐directed to east‐directed occurs instead in the middle Diamante Formation and may reflect the Late Cretaceous transition from forebulge derived sediment in the distal foredeep to proximal foredeep material derived from the thrust belt to the west. This change in palaeoflow represents the migration of the forebulge, and therefore, of the foreland basin system between 80 and 90 Ma in the Malargüe area.  相似文献   

Unusual megafaunal assemblages on the continental slope off Cape Hatteras     

Barbara Hecker 《Deep Sea Research Part II: Topical Studies in Oceanography》1994,41(4-6)

Megafaunal assemblages were studied in August–September 1992 using a towed camera sled along seven cross-isobath transects on the continental slope off Cape Hatteras. A total of 20,722 megafaunal organisms were observed on 10,918 m² of the sea floor between the depths of 157 and 1 924 m. These data were compared with data previously collected off Cape Hatteras in 1985 and at other locations along the eastern U.S. coast between 1981 and 1987. Megafaunal populations on the upper and lower slopes off Cape Hatteras were fouond to be similar, in terms of density and species composition, to those observed at the other locations.In contrast, megafaunal abundances were found to be elevated (0.88 and 2.65 individuals per m² during 1985 and 1992, respectively) on the middle slope off Cape Hatteras when compared to most other slope locations (<0.5individuals per m²). These elevated abundances mainly reflect dense populations of three demersal fish, two eel pouts (Lysenchelys verrilli andLycodes atlanticus) and the witch flounderGlyptocephalus cynoglossus, and a large anemone (Actinauge verrilli). These four species dominated the megafauna off Cape Hatteras, whereas they represented only a minor component of megafaunal populations found at other slope locations. Additionally, numerous tubes of the foraminiferanBathysiphon filiformis were observed off Cape Hatteras, but not elsewhere. The high density of demersal fish found off Cape Hatteras appears to be related to the high densities of infaunal prey reported from this area. The high densities ofA. verrilli andB. fuliformis may be related to the same factors responsible for the high infaunal densities, namely enhanced nutrient inputs in the form of fine particles. Extreme patchiness also was observed in the distributions of the middle slope taxa off Cape Hatteras. This patchiness may reflect the habitat heterogeneity of this exceptionally rugged slope and the sedentary nature of the organisms inhabiting it.  相似文献   

Numerical modelling of the morphological response induced by low-crested structures in Lido di Dante,Italy     

Barbara Zanuttigh 《Coastal Engineering》2007

This paper analyses the morphological response induced by low-crested structures on the adjacent seabed, with particular interest in the erosion patterns that frequently develop at gaps and roundheads. The mechanisms responsible for erosion processes are examined by means of morphodynamic simulations with the numerical suite MIKE 21 CAMS developed by DHI Water & Environment. The main purpose of the paper is to verify how and how far a commercial code can predict bed evolution, in vicinity of defence structures in a real case, in order to get information that may be very useful for structure design and possible maintenance of existing works. The code is applied to a long-term simulation on a study site that is characterized by a composite intervention and suffers from severe erosion, Lido di Dante (Italy). The simulation covers the period (one year and a half) between two available multi-beam surveys, in order to have a detailed real bathymetry as starting point and another one, as accurate as the first, to compare numerical with surveyed results. All the other input data for the model, as waves, tide, wind and sediment characteristics, are derived from measurements in the area; moreover, the code is calibrated using wave and current data acquired during a field campaign. The bed evolution derived from simulations shows a good agreement with the survey both in the locations and in the intensity of erosive and depositional areas. A sensitivity analysis of results to some selected modelling parameters is performed on a shorter simulation period (one month), showing that accounting for bed slope in sediment transport modelling has greater effects in bathymetry evolution than the use of a complex sediment bathymetry or the representation of wave diffraction.  相似文献